When I bought new Barr Marine manifolds and elbows to replace the one piece OMC V6 units, after I removed the paint they were perfect, couldn't even get a .001" feeler blade in under the straight edge anywhere. Here's what a new manifold looks like...
one more tip, if re-using the old manifolds, before installing the elbows make sure the bolts will thread all the way in, so you get good & even clamping force, if not clean out the threads with a thread chaser. Follow the manufacturer of the gaskets instructions on sealer/no sealer and torque. As you can see I used a pair of longer bolts with the heads cut off to make it easier to install the manifolds, much easier that way. After cutting the heads off the bolts, I cut a slot in the stub to make it easy to remove with a screwdriver. You thread in the 2 headless bolts, slide on your gasket, slide on the manifold, install the other bolts, then remove the 2 headless bolts and install the last 2 bolts then torque all to spec.