I have heard charging them off of an outboard is a problem.
not sure I want something that can burst in to flames and impossible to put out a good thing
Charging fully off an outboard alternator depends on the programming of the regulator. You can get around this with a DC-DC charger that is designed to properly charge LiFePO batteries.
Lithium batteries currently come in 2 different battery chemistries. Lithium-ion is more power dense, and is used in phones, power tools, and most electric vehicles. If case gets cracked, battery can catch fire when exposed to oxygen, and is very difficult to extinguish.
LiFePO (lithium iron phosphate) is a very different chemistry, and is very stable. It is used for 6, 12, 24, 48 volt lead acid replacement, I have never heard of one catching fire. It is used in RVs and boats and golf carts with an enviable safety record. While not as energy-dense as lithium ion, LiFEPO batteries are 1/3 the weight of lead acid, and have proven life spans of 10X the number of battery cycles (typically in the thousands depending on application). LiFePO is NOT usually a good substitute for starting high hp motors because the BMS holds loads to under 50A, or 100A on the better BMS, but is very well suited for house batteries and running trolling motors.