Re: Best Prep For Re-gel Coating?
BillP
My intent is not to create an argument with you, only to give accurate information, and I know that many of the things people believe about gel coat and resin have a grain of truth, but are not exactly correct.
If you read any information on applying gel coat (from the manufacturer) it will say 18 to 20 (or very close to that) mils and only slightly more on hulls to help prevent blistering. Anything over 30 is in the danger zone for cracking, less is not an issue for cracking if it's cured well. The thicker amounts you talk about can be used in tooling, one reason is molds are supposed to be made more ridgid than a part, so they should see less flexing, which means less cracking, so the gel coat can be thicker. Another reason is that many molds get sanded after they're made, so there needs to enough gel coat to sand and buff it a few times during it's lifetime. Thicker gel coat can also help keep the glass from printing through to the surface, but the thicker gel coat is made possible by having less flex in the mold.
In lab testing it's been proven time after time that thicker gel coat tends to yellow sooner than thinner gel coat.
I know of no high end boat builders that thin their resin with styrene, we sell them the resin at the correct viscosity for them to use in there plant. Nor do I know of any resin manfacturer that says to thin it with styrene.
Adding more stryrene doe's not improve resin, as I said before it degrades it, adding more than just a few percent can weaken and lessen it's water resistance. If a lower viscosity resin is needed, then it's always best to have the resin manufacturer sell you one formulated how you need it.
At one time resin was typically from around 40% to as high as almost 50%
styrene, now the majority of it is 35%, this is due to federal regulations. The % is not important part though, it's that it was formulated to have that % for best performance, not more or less. Small shops and most retail outlets can still use the higher styrene resins in most areas of the country, so if you start with 40 to 50% styrene and then start adding more, you end up with very little actual resin in the mix and the resin is where the strength is.
We do find that many shops, or at least some of the people in their repair departments, like to concoct methods of thinning the gel coat to spray it for doing repairs, that's noramlly why we're called in to do a repair class.
If there are 10 people doing repairs, we typically find 3 of them have very few problems and their repairs turn out well almost all of the time. 4 or 5 will have more problems, but still not bad, the remaining few have problems all the time, with very inconsistent results. These last few rarely follow the recommended methods or measure anything, they use the glug glug method, just pour it in until it looks right, then sort of mix it. Adding styrene and acetone are 2 of the things that create those problems and it takes less of them than you might think. If you follow the recommeneded methods of using the correct products you will get much more consistent and long lasting results.
The styrene helping the bond opinion has more merrit. Styrene can start to break down resin that is not thoroughly cured (it can damage cured resin also, but takes much longer) and depending on the type of resin may have more or less of an affect. But it doe's not reactivate the resin, I know you didn't say this, but that's a term many people use. Styrene can do a very good job of cleaning the surface, and like Tail Gunner found out when painting his boat, acetone evaporates very fast and may not clean the surface adequately. Styrene does not evaporate as quickly and can do a better job of cleaning the surface. If you were sanding the parts correctly, then you should have been getting a very good bond. When bonding with ployester resin the bond may be very good, the problem is the resin is brittle and weak compared to the glass fibers it's designed to be used with. So when it's used without glass, what normally fails is the resin layer between the two parts being glued, not the bond, the surface of each part will typically still have resin stuck to it after it's been broken apart. There is also a huge difference in the strength of different types of polyester resins, so depending on the resin used the results may very.
These are not just my opinions, they are also from the chemists in our lab that formulate and test the products we make.
I must say that a few years ago I did ask them to test the styrene helping the bond issue again, but I don't think they did. I just wanted more testing done in this area. I do feel that if styrene is used, then at least whatever amount of it is left on the surface will not be as much of a contaminate as other products might be.