Did she overheat at engine speed below 2000RPM or above, or both?
The poppit starts working at about 2000RPM, when water pressure is strong enough to open it.
The thermostat cools the engine at about 2000RPM or less. Check them for proper operation. I get about 7 or 8 years on a set, in saltwater.
The water pump impeller cools the engine at all speeds. If your's is older than 5 years or so, it is likely time to rebuild it.
Also, put a torque wrench on the head bolts and check 'em for proper tightness. Those old V6 motors tended to have them loosen over time. Compression leaks into the cooling passages cause overheat.
I also flushed my engine cooling passages this spring. It had some buildup in the cooling passages, that I could feel with my finger in the thermostat holes. Not enough to cause issue, but enough where I did not want any more buildup.