I don't understand, why would you want to ground a spark plug wire? I know that some guys ground the spark plug itself (still connected to the wire) to the outside of the motor when the are checking for spark but, I don't know why you would want to ground the wire.
I either use test leads as mentioned, shove one of the alligator clips in the boot, other end to the powerhead.
If I am at home, I use my inline adjustable spark tester, set the gap to 0". Get your moneys worth out of your tool.