yes, if you are bored and have the tools
not much of a gain with a stock bump-stick and 5000 RPM limit
on vortec heads, blend the intake bowls and runners, leaving the passages rough (carbide only) while tapering around the valve guide boss
the exhaust should be bowl blended and port matched (not gasket matched) and sanded with tootsie rolls to 220 finish
This will help some throttle response and pick up some flow in the 3200-4500 RPM range
for detonation control, the combustion chamber should have all the casting marks removed and sanded with 180-220 grit minimum.