Re: battery isoalator
If the orange wire you are talking about goes from the alternator output to the starter or battery 1 then that is the right wire.
Depending on where you put the isolator you could take the wire off the alternator and put on isolator battery one post. Then take a new wire the same size or one size bigger and run from the alternator to the isolator common post. Last run another wire from the isolator battery 2 post to the second battery. Again should be the same size.
A few saftey tips before you start disconnect both battery ground wires from the batteries. Also when done get some rubber connection covers to cover all the post on the back of the isolator so nothing can short out to the 12 volts connections.
When all done clean ground post and reconnect to both batteries.