Exhaust shutters are stainless steel. They are expected to keep water from surging into the exhaust passage, if you drop from high speed suddenly. Mine broke and fell off years ago. Just don't abruptly come down from high speed, and water will not enter the engine.
As for the double antifreeze process. it clearly doesn't hurt anything, but it is unnecessary. Simply drain the motor of water. Make sure to clear the drains with a nail or awl, before draining. After all the water drains, add some antifreeze into each hose, until you see the color of the AF emerge from a drain. That will chase the water out.
On a standard Mercruiser raw water cooled V6/V8, antifreeze will emerge from each of the two block drains, 2 manifold drains and 2 riser drains. In addition, you want A-F to emerge from the exhaust (thru prop), the cooling water out gratings above the antiventilation plate, and the raw water intake holes in front of prop on gearcase.
Now install the plugs and fill the manifolds, risers and block.