On the DVA working on a 6 rather than a 4, the pulses are closer together on a 6 by 33% meaning that it would be 33% easier for the DVA to measure the 6 than the 4. On peak voltage whatever it is, regardless of number of cylinders the DVA will charge up to it and hold till you disconnect the leads or turn the engine off. The only difference with number of cylinders being measured is how long it takes to stabilize at the peak voltage reading on the meter as a function of engine rpms.
On the '88 115 Direct Injection, I had one, bought new, marketed in 1989 on a 1989 Ranger pad hull. That sucker would get on the pad and run at 6k rpm, Merc 19P Laser 3 blade SS, kissing 50...maybe would have touched it if in the dead of winter (brrrrrrr), about 10% prop slip, and just sing to me. Loved that engine and boat more than any I ever owned and that's quite a few over the years. I ran the 19 vs higher pitch because I used to water ski behind it also.