They have to have a vent somewhere, you can't weld on a closed cylinder.
Either all the chambers are vented to each other and there is a plug at the back or there is a plug on top of each chamber but there has to be a plug somewhere.
Most tubes with chines are both in and outside, inside they actually work better because the outside of the tube is not in the water in a turn.
And there is no clean water under a toon, with the wake from each tube hitting the bottom of the boat it is very turbulent under there.
Some companies run a few pounds of air in tubes, actually makes them more resistant to dents but no more than 3-4 psi.
And no, it will not help them float better, the only way to increase buoyancy is to increase the actual size of the tubes.