Kill switch would have an alarm with key on and would never start.
45 psi engine key on engine off? Pressure should drop to 37 or so at idle.
Can you hear the fuel pump run with key on engine off? Pump should run for 5 seconds or so.
I would do a pressure test key on engine off then verify running pressure with the engine running.
How does it behave when you pump the primer bulb up hard before starting?