Yea no signs of obvious gasket failure. I'm thinking the exhaust manifold is leaking into the combustion chamber and whatever cylinder has an open intake valve is letting the water go into the intake and sit.
Water would not have came into the intake and just sit and make a rust line like this. Had to have came in after killing the motor.
So your saying water runs up hill and does not flow back down into the other intake ports
That is the head water jacket
Reassemble and pressure test. Pulling the heads makes it impossible to know if there is a crack unless in an obvious spot.